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the initial enol is the result of 'conjugate' or 1,4-addition. The enol tautomerizes to the more stable keto form
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- more acidic than an aldehyde, ketone, or ester, because its conjugate base is stabilized (resonance) by the presence of the two carbonyls
- a strong nucleophile (NU-) attacks what type of carbon?
- has a lower activation energy for formation (carbonyl has larger delta plus). If nucleophile adds irreversibly, the 1,2-kinetic product dominates